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You should not need to set up anything in your you application to handle this and the link you provided for the library is not appropriate for use with MongoDB as it is a relational back end solution.
The first case here is do you actually have a Replica Set Configuration for MongoDB? I can only answer presuming that you but the link is worthwhile reading as from your question you probably do not have a core understanding of MongoDB Replication concepts.
What will be explained there is that there is no Secondary for your application to failover to, what actually happens is the Replica Set itself elects amongst it’s members which node will become the Primary.
Going on with the answer, you configure your application to handle the failover through settting up your Connection String to the driver. Read through that documentation and you will find that among other useful things, you are basically providing a list of hostnames which will be members of the Replica Set. You don’t need all the members, but just enough to be a seed list so that the other nodes can be discovered. That would just happen anyway with the correct options, but it is good practice to have more than one host to contact even to get that information. Here’s a sample:
mongodb://<Primary>,<Secondary>/<database>
You may possibly want to take a look at MongoEngine, considering you probably have experience with django and it uses modelling concepts that you will be familiar with, whilst still allowing access to MongoDB features. There is some documentation there on setting up Replica Set connections from memory.