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You are trying to send a xlrd.book.Book object, not a file.
You used xlrd to do your things in the workbook, and then saved to a file.
workbook = xlrd.open_workbook(path)
#... do something
workbook.save(path)
Now you send it like any other file:
with open(path, 'rb') as f:
response = HttpResponse(f.read(), content_type="application/ms-excel")
response['Content-Disposition'] = 'attachment; filename={}_Report{}'.format(testname, extension)
Source:stackexchange.com